Renewable power generation facilities are constantly expanding due to the expected depletion of fossil fuels and the increasingly demanding policy of pollution control. Having said that, hydrogen is one of the promising energy sources. That said, hydrogen chain safety is an unescapable parameter that should continuously coexist with the development of hydrogen domain. In this context, this article presents a contribution to the risk analysis and evaluation of a complex hydrogen production system ’EGA-9000' at CIEMAT (Centre for Research on Energy, Environment and Technology - Madrid, Spain). The methodology followed in this study revolves around the risk analysis process through a FAST (Functional Analysis System Technique) functional analysis method and a HAZOP (HAZard and Operability) dysfunctional analysis method. The evaluation of the thirty-three scenarios identified by the risk analysis shows that the studied system is insecure. Indeed, five scenarios at an unacceptable level of risk. And it is noted that the risk of fire and explosion is the major risk for all scenarios studied. To this end, safety measures (recommendation) have been proposed based on the weaknesses detected by the risk analysis carried out.